Many researchers rely heavily on Google Scholar to find articles. They will then search for the references found in those articles, and the "cited by" links, to expand their search. Sometimes this works really well, other times, less so. (The "less so" is what keeps librarians nice and busy!)
Google and Google Scholar are powered by proprietary algorithms. Because the systems are proprietary, it's difficult to know if we are getting a complete picture of what has been published on a given topic.
Library databases match your keywords to words in the title, subject headings, and abstracts (summaries) of the articles in the journals indexed by the database. Some databases also look for your keywords in the full text of the article. You will find things you didn't find in Google Scholar, and sometimes you will find things in Google Scholar that you didn't find in a database.
The takeaway? Don't limit yourself to one tool!
Search tips:

The Articles & Full Text feature on the main Library web page allows you to perform simple searches across multiple databases. Because the various databases are structured differently, search results may vary widely. For more precise searching, it's best to search the databases individually. Choosing Databases will display a listing by subject area.
Not all articles are available full text! If an article isn't available full text through a database...
Access Anywhere is a bookmarklet that lets you quickly authenticate as a CU person, when you're off-campus. This allows you to access databases.